Adhesive & Sealant Intermediates
Formulating Intermediates: Advancing Adhesive and Sealant Technologies
Discover our adhesive and sealant intermediates. From acrylics and silicones to polyurethanes and polyolefins, solve your most complex formulating challenges with Dow’s advanced adhesive and sealant intermediates.
Our broad portfolio empowers formulators to achieve robust adhesion on difficult substrates and long-term durability in harsh environments. Achieve your performance and sustainability targets with diverse chemistries. Tune formulations for their intended application and improve processing efficiency with Dow intermediates.
Polymers
Polydimethylsiloxane polymer with reactive silanol functionality is the backbone for silicone sealant and adhesive technology. Dow offers a range of OH polymers, allowing flexibility to adjust formulations to application requirements.
Plasticizers
Plasticizers for silicone-based sealant and adhesive formulations adjust the viscosity, allowing easier application and extrusion of the final formulation. Silicone plasticizers can soften cured materials by increasing elongation and reducing modulus.
Solvent
Cyclotetrasiloxane is a volatile methylsiloxane fluid, that is clear, odorless, has low toxicity, low surface tension; and evaporates completely at room temperature. This solvent helps the delivery of silicone sealants and coatings before evaporating completely.
Dow offers a variety of formulated acetoxy sealants. The XIAMETER™ branded Acetoxy Sealants are available in bulk, drums, and private labeled cartridges.
Available in the Americas
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| Product | Extrusion Rate, g/mi | Tensile Strength at Break, PSI (kg/cm2) | Tack Free Time, minute | Elongation at break, percent | Durometer, Shore A |
364 | 264 | 13 | 499 | 25 | |
370 | 266 | 14 | 508 | 25 | |
362 | 265 | 13 | 509 | 25 | |
|
| 375 | 266 | 13 | 501 | 24 |
|
| 632 | 232 | 13 | 512 | 21 |
Available in Europe
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Product | Extrusion Rate, g/min | Tensile Strength at Break, PSI (kg/cm2) | Tack Free Time, minutes | Elongation at break, percent | Durometer, Shore A
|
174 | - | 22 | 745 | 21 | |
XIAMETER™ SLT-5032 Sealant Acetoxy | 174 | - | 22 | 745 | 21 |
397 | - | 18 | 475 | 25 | |
400 | - | 18 | 460 | 24 | |
397 | - | 18 | 475 | 25 | |
374 | - | - | 476 | 18 | |
817 | - | - | 480 | 13 | |
XIAMETER™ SLT-5531 Sealant Acetoxy | 1980 | - | 17 | 650 | 14 |
799 | 1.4 | 11 | 550 | 17 | |
768 | - | - | - | - | |
XIAMETER™ SLT-5260 Sealant Acetoxy | 384 | 1.8 | 11 | 400 | 29 |
Available in Asia
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Product
| Extrusion Rate, g/min | Tensile Strength at Break, PSI (kg/cm2) | Tack Free Time, minute | Elongation at break, percent | Durometer, Shore A |
799 | 1.4 | 11 | 550 | 17 | |
768 | - | - | - | - | |
XIAMETER™ SLT-5260 Sealant Acetoxy | 384 | 1.8 | 11 | 400 | 29 |
- | - | - | - | - |
Explore Silane
Silanes are versatile additives in adhesive and sealant formulations, capable of delivering multiple functions including adhesion promotion, crosslinking, moisture scavenging, and more.
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| Product | Functionality | Chemical Name | CAS | Purity |
Amino/Methoxysilane | Aminoethylaminopropyltrimethoxysilane; AEAPTMS | 1760-24-3 | - | |
Methacryl/ Methoxysilane | Methacryloxypropyltrimethoxysilane; MAPTMS | 2530-85-0 | 99-100 % | |
Epoxy/Methoxysilane | Glycidoxypropyltrimethoxysilane; GPTMS | 2530-83-8 | 98.5% Min | |
Alkoxy | Methyltrimethoxysilane; MTMS | 1185-55-3 | 95% Min | |
Acetoxy | Methyl and ethyl triacetoxysilane | 4253-34-3 and 17689-77-9 | MeSi(OAc)₃ -min 40% and EtSi(OAc)3 – min 45% | |
Amine | Hexamethyldisilazane | 999-97-3 | 99-100% | |
XIAMETER™ PMX-0930 Silanol Fluid
| Hydroxy | Hydroxy-terminated polydimethylsiloxane | 70131-67-8 |
99-100% min |
Amino/Methoxysilane | Aminoethylaminopropyltrimethoxysilane; DAMO | 1760-24-3 | 97% min |
Intermediates for Silane Modified Hybrid Formulations
Dow has Silane Modified Polymers, silanes, diluents, and plasticizers for hybrid formulations. The hybrid sealants allow customers to incorporate desired properties found in silicone with inherent properties of polyether and polyurethane chemistries. Dow offers a range of intermediates required for formulating and is innovating to help the industry develop formulations to address the most challenging needs.
Hybrid Polymer
Utilize hybrid polymers to experience the benefits of silane reactivity while maintaining paintability and strength. Hybrids are differentiated by their distinct polymer structure where organic polymer backbones are functionalized with silanes. Structure types are silane-terminated polyurethane structures and silane-terminated polyether structures. Innovation in the polymer structure has advanced over time, and this innovation has helped hybrid formulations expand to new applications. Whether you are looking to develop a robust general-purpose adhesive or differentiate with distinct properties, Dow has you covered.
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| Product | Viscosity mPa-s | Functionality (Dimethoxy vs Trimethoxy) | Polymer Structure |
10,000 | TMS - STPU | Linear | |
33,000 | TMS - STPU | Linear | |
| DOWSIL™ HP - 200 POLYMER | 8,000 | DMS - STPE | Linear |
7,000 | DMS - STPE | Linear / Partially Branched | |
15,000 | DMS - STPE | Branched | |
45,000 | TMS - STPE | Linear | |
57,000 | TMS - STPE | Linear |
Silanes are versatile additives in adhesive and sealant formulations, capable of offering multiple functions including adhesion promotion, crosslinking, moisture scavenging, and more.
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| Product | Functionality | Chemical Name | CAS |
Amino/Methoxysilane | Aminoethylaminopropyltrimethoxysilane; AEAPTMS | 1760-24-3 | |
Amino/Methoxysilane | Aminopropyltrimethoxysilane; APTMS | 13822-56-5 | |
Epoxy/Methoxysilane | Glycidoxypropyltrimethoxysilane; GPTMS | 2530-83-8 | |
Methacryl/ Methoxysilane | Methacryloxypropyltrimethoxysilane; MAPTMS | 2530-85-0 | |
Alkoxy | Methyltrimethoxysilane; MTMS | 1185-55-3 | |
Amino/Methoxysilane | Aminoethylaminopropyltrimethoxysilane; DAMO | 1760-24-3 |
Plasticizers and diluents can be used to increase product flexibility and elasticity, improve processability and dispersion, as well as optimize costs.
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| Product | Type | Equivalent Weight (g/eq) | Viscosity at 100°F cSt |
Polyether Diol | 500 | 70 | |
Polyether Diol | 2000 | 480 | |
Polyether Diol | 1000 | 200 | |
Polyethylene Glycol | 600 | 11 (@100° C) | |
Mono-γ-Trimethoxysilane-modified polymer | 6650 | 1600 (mPa.s@25° C) | |
Polyether Triols | 1650 | 415 | |
Polyethylene Glycol | 1000 | 17 (@100° C) |
Dow is an integrated supplier of polyether polyol and MDI with operations around the world for global supply. Our regional technical support and variety of distribution partners can help make sure your unique adhesive and sealant formulation needs are met.
Dow polyether polyols include:
- Standard diol and triol building blocks
- Low monol polyols to improve tensile strength and elongation
- EO-capped polyols to enhance reactivity and hydrophilicity
- Hydrophobic polyols offer water resistance
- High functional polyols to achieve greater rigidity
- Amine-initiated polyols for catalytic behavior to potentially reduce catalyst loading
The isocyanate portfolio complements these polyols with a variety of monomeric, polymeric, and modified MDI grades.
Off-the-shelf MDI-based prepolymers are also available as intermediates for a one-component formulation with additives or as one part of a two-component solution. Our prepolymer manufacturing capabilities are flexible to expand our offering as your needs evolve.
Standard diols & triols
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| Product | Nominal Functionality | Equivalent Weight (g/eq) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 2000 | 455 | Sealant | |
2.0 | 1000 | 150 | Adhesive, Sealant | |
2.0 | 500 | 70 | Adhesive | |
2.0 | 216 | 35 | Adhesive | |
3.0 | 1000 | 475 @ 77ºF | Adhesive, Sealant | |
3.0 | 500 | 130 | Adhesive | |
3.0 | 235 | 110 | Adhesive | |
3.0 | 85 | 300 | Adhesive |
Low Monol Polyols
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| Product | Nominal Functionality | Equivalent Weight (g/eq) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 4000 | 1900 | Sealant | |
2.0 | 2000 | 480 | Adhesive, Sealant | |
2.0 | 1000 | 200 | Adhesive, Sealant | |
2.0 | 500 | 170 @ 77ºF | Adhesive |
EO-Capped Polyols
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| Product | Nominal Functionality | Equivalent Weight (g/eq) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 2000 | 410 | Adhesive, Sealant | |
2.0 | 1000 | 170 | Adhesive, Sealant | |
3.0 | 2000 | 640 | Adhesive, Sealant | |
3.0 | 2000 | 650 | Adhesive, Sealant | |
3.0 | 1650 | 415 | Adhesive, Sealant | |
3.0 | 1550 | 400 | Adhesive, Sealant |
Hydrophobic polyols
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| Product | Nominal Functionality | Equivalent Weight (g/eq) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 1000 | 470 @ 77ºF | Adhesive, Sealant | |
3.0 | 200 | 330 @ 77ºF | Adhesive |
Amine-Initiated Polyols
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| Product | Nominal Functionality | Equivalent Weight (g/eq) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 106 | 6000 | Adhesive | |
4.0 | 70 | 3550 | Adhesive, Sealant | |
4.0 | 1700 | 1100 @ 77ºF | Adhesive, Sealant |
Monomeric MDI
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| Product | Approximate Functionality | % NCO | Isocyanate equivalent weight (g/eg) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 33.5 | 125 | Solid | Adhesive, Sealant | |
2.0 | 33.5 | 125 | 10 | Adhesive, Sealant |
Polymeric MDI
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| Product | Approximate Functionality | % NCO | Isocyanate equivalent weight (g/eg) | Viscosity at 100ºF (cSt) | Applications |
2.3 | 32.7 | 128 | 30 | Adhesive | |
2.3 | 32.0 | 131 | 50 | Adhesive | |
2.5 | 31.5 | 133 | 85 | Adhesive | |
2.7 | 31.4 | 134 | 180 | Adhesive | |
3.0 | 30.8 | 136 | 700 | Adhesive | |
3.2 | 30.2 | 139 | 1800 | Adhesive |
Modified and Formulated MDI
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| Product | Approximate Functionality | % NCO | Isocyanate equivalent weight (g/eg) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 33.2 | 126 | 15 | Adhesive, Sealant | |
2.1 | 29.1 | 144 | 33 | Adhesive, Sealant | |
2.2 | 32.8 | 128 | 25 | Adhesive |
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| Product | Approximate Functionality | % NCO | Isocyanate equivalent weight (g/eg) | Viscosity at 100ºF (cSt) | Applications |
2.0 | 23.1 | 182 | 770 | Adhesive | |
2.0 | 18.6 | 225 | 1400 | Adhesive | |
- | 26.0 | 162 | 150 | Adhesive | |
VORASTAR™ HB 6724 | - | 21.5 | 195 | 425 | Adhesive |
HYPERLAST™ LP 5608 | - | 19.5 | 215 | 1000 | Adhesive |
VORASTAR™ HB 6042 | - | 16.0 | 263 | 700 | Adhesive |
HYPERLAST™ LP 5601 | - | 15.0 | 280 | 500 | Adhesive |
HYPERLAST™ LP 5612 | - | 12 | 350 | 1000 | Adhesive |
HYPERLAST™ LE 5006 | - | 10.0 | 420 | 2300 | Adhesive |
Acrylic Polymers for Caulks and Sealants
When it comes to caulk and sealants, you need to be able to trust in your products’ ability to perform.
Dow’s comprehensive range of acrylic and styrene acrylic polymer emulsions for caulk and sealants allows you to formulate sustainable products that address the industry’s ever-changing performance demands. Confidently formulate to ASTM C834 and C920 Class 12.5 to Class 35 standards with Dow's Acrylic polymer offerings.
North America
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| Product | ~Tg, degrees C (onset) | Solids, % | Polymer Chemistry | Sustainability |
-13 | 58 | 100% Acrylic | ~32% bio-based carbon content | |
-26 | 62 | 100% Acrylic | ~20% bio-based carbon content | |
-49 | 63 | 100% Acrylic | Enables plasticizer-free formulation | |
-2 | 55 | 100% Acrylic | ~34% bio-based carbon content | |
-2 | 62 | 100% Acrylic | ~36% bio-based carbon content | |
+5 | 62 | Acrylic-Styrene Copolymer | - | |
-43 | 63 | 100% Acrylic | Enables plasticizer-free formulation | |
+5 | 55 | Vinyl-Acrylic | - | |
+13 | 47 | 100% Acrylic | - | |
+13 | 47 | 100% Acrylic | - |
Latin America
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| Product | ~Tg, degrees C (onset) | Solids, % | Polymer Chemistry | Sustainability |
-49 | 63 | 100% Acrylic | - Enables plasticizer-free formulation | |
+5 | 62 | Acrylic-Styrene Copolymer | - | |
-43 | 63 | 100% Acrylic | - Enables plasticizer-free formulation | |
-2 | 62 | 100% Acrylic | ~36% bio-based carbon content | |
-26 | 62 | 100% Acrylic | ~20% bio-based carbon content | |
-35 | 62 | 100% Acrylic | - | |
+5 | 62 | Acrylic-Styrene Copolymer | - |
Europe
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| Product | ~Tg, degrees C (onset) | Solids, % | Polymer Chemistry | Sustainability |
-26 | 62 | 100% Acrylic | ~20% bio-based carbon content | |
-35 | 62 | 100% Acrylic | - | |
+5 | 62 | Acrylic-Styrene Copolymer | - | |
-2 | 62 | 100% Acrylic | ~36% bio-based carbon content | |
+8 | 50 | Acrylic-Styrene Copolymer | - | |
-27 | 61 | 100% Acrylic | - | |
-1 | 50 | Acrylic-Styrene Copolymer | - |
Asia Pacific (APAC)
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| Product | ~Tg, degrees C (onset) | Solids, % | Polymer Chemistry | Sustainability |
-26 | 62 | 100% Acrylic | ~20% bio-based carbon content |
Additives for Acrylic Caulk & Sealant Formulations
Dispersants
Dow offers several different types of dispersants for your waterborne caulks and sealants formulating needs: polyacid, hydrophilic copolymer, hydrophobic copolymer, and polymeric dispersants.
Rheology Modifiers
Dow offers a range of rheology modifier chemistries, ASE, HASE, HEUR and Cellulosics for your formulating needs. They function as thickeners, suspension aids, offer flow control, and can prevent syneresis.
Surfactants
Dow surfactants include some of the most familiar anionic and nonionic products in the industry, known worldwide for excellent emulsification and dispersion. Our investments in surfactant products and technology create one of the strongest capability platforms in the industry while offering more sustainable and safer product alternatives.
Hot Melt Adhesive Intermediates for Every Application
Dow leverages decades of industry experience to produce high-performance polymers for your hot melt adhesive (HMA) needs. The global HMA industry is evolving with trends demanding innovative options across various applications.
Our versatile product families – AFFINITY™ GA Polyolefin Elastomers, INFUSE™ Olefin Block Copolymers, ENGAGE™ Polyolefin Elastomers, and ELVAX™ Ethylene Vinyl Acetate Copolymer – are tailored to address specific customer needs, production processes, and end-use applications.
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| Polyolefin Products for Packaging, Hygiene, and Pressure Sensitive Adhesives | Melt Index, 190 oC, 2.16 kg (g/10 min) | Density (g/cm3) |
500 | 0.87 | |
1000 | 0.87 | |
1250 | 0.87 | |
650 | 0.87 | |
15 | 0.86 | |
15 | 0.86 | |
30 | 0.88 | |
5 | 0.87 | |
13 | 0.86 |
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| Bio-circular, ISCC PLUS-certified Products | Melt Index, 190 oC, 2.16 kg (g/10 min) | Density (g/cm3) |
500 | 0.87 | |
1000 | 0.87 | |
1250 | 0.87 | |
5 | 0.87 |
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| Ethylene-Vinyl Acetate Products | Vinyl Acetate Content (wt %) | Melt Index, 190 oC, 2.16 kg (g/10 min) | Density (g/cm3) |
18 | 8 | 0.941 | |
18 | 30 | 0.927 | |
18 | 150 | 0.937 | |
ELVAX™ 410 Ethylene Vinyl Acetate Copolymer | 18 | 500 | 0.934 |
25 | 19 | 0.948 | |
28 | 6 | 0.955 | |
28 | 25 | 0.950 | |
28 | 43 | 0.951 | |
28 | 150 | 0.951 | |
28 | 400 | 0.951 | |
32 | 43 | 0.957 | |
40 | 50 | 0.965 |
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Terpolymer’s with 1% MMA | |||
| ELVAX™ 4260 Ethylene Vinyl Acetate Copolymer | 25 | 6 | 0.955 |
| ELVAX™ 4310 Ethylene Vinyl Acetate Copolymer | 25 | 500 | 0.945 |
Stay informed on our newest innovations
Henkel & Dow Cut Adhesive Emissions
Henkel and Dow cut hot melt adhesive emissions by up to 40% using low-carbon feedstocks and renewable energy in their ongoing collaboration.
Dow & Henkel Advance Bio-Based Packaging
New generation adhesives feature bio-based content, supporting circular and low-carbon goals.
FAQs: Adhesive & Sealant Intermediates
Improved adhesion can be accomplished through two means, in formulation through the addition of a silane such as amino-silanes (OFS-6020 Silane), epoxy-silanes (OFS-6040 Silane), methacryl-silanes (OFS-6030 Silane) or during the sealant application by employing adhesion improvement techniques such as chemical treatment, primer application, roughing the surface, corona or plasma treatment, good adhesion can be achieved.
Silicone sealants and organic sealants with 100% acrylic polymer inherently have good UV resistance. For organic sealants, such as acrylics and polyurethane, UV resistance can be improved by incorporating UV additives in the formulation. Additionally, silicones are known for their consistent properties over a wide range of temperatures, making them suitable for outdoor durability. If the sealant needs to be painted, a hybrid, acrylic, or polyurethane sealant can be used.
Improved cure speed is dependent on the sealant and adhesive chemistry. For silicones, after fine tuning the amount of catalyst and crosslinker, in room temperature vulcanized products, we recommend optimizing humidity. For two-part adhesives and sealants, you can increase the ratio of catalyst to base. For acrylics, drier conditions combined with moderately higher temperature may be able to accelerate cure.
Causes of yellowing may differ by chemistry and by the surrounding environment. Sunlight (UV), heat, oxidation and exposure to a variety of chemicals (dyes, additives, detergents, acids, alkalis) can all contribute to yellowing. Some addition cured products may experience heat-induced discoloration from the catalyst. Yellowing may be reduced by the addition of UV-absorbers, UV-stabilizers, and antioxidants.
For strength, polyurethane can be formulated to be ultra-low VOC. Other low VOC options are silane-modified polyurethane, silane-modified polyether, and silicone chemistries, and acrylic polymers which are intrinsically very low-VOC and can be formulated into a low-VOC sealant.
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