Separation of Osmium from Liquid Media
Acidic Halogen Leach
Many mining projects are underway in which ores are leached under oxidizing and acidic conditions. Under these conditions, DOWEX™ Anion Exchange Resins have proven to be tough, steady performers.
In chloride solutions osmium forms very stable chloroanion complexes which are readily adsorbed on strong base anion exchangers such as DOWEX™ 21K XLT Resin. Interestingly, like the PGMs, osmium is also strongly adsorbed on weakly basic anion exchange resins such as AMBERLYST™ A21 Resin. Weakly basic anion exchangers are often effective in their conjugate acid forms (in acidic media) or in their free-base forms (neutral ligand-metal complexes). Elution of osmium from the resin can generally be accomplished with dilute acid solutions that do not elute other platinum group metals. Fuming of osmium loaded resins is not recommended as the volatile osmium can carry away other PGMs.
Additional information about the recovery of precious metals from acidic halogen leach solutions and about fuming can be provided by contacting Dow.
Caution: Osmium (Os) compounds are generally volatile (some sublime) and are extremely toxic. As with all metal solutions, those containing Os should be handled using appropriate personal protection.