NC Substitution

In contrast to other cellulose-based products, in the case of nitrocellulose the degree of substitution is indicated indirectly via the nitrogen content (in relation to dry substance). Theoretically, a nitrogen content of 14.14% is possible (all three positions in an anhydroglucose unit are converted, i.e. substituted).

In actual practice, the nitrogen content cannot exceed around 13.6 to 13.8%. The nitrogen content of WALSRODER™ Nitrocellulose and WALSRODER™ NC-Chips for coatings and printing inks is between 10.7 and 12.3%. Nitrocellulose with a nitrogen content above 12.6% is classed as an explosive.
The degree of substitution determines the solubility of WALSRODER Nitrocellulose and WALSRODER NC-Chips in organic solvents. Walsroder Nitrocellulose and Walsroder NC-Chips are divided up according to their solubility as follows:

 

A grades
 
Nitrogen content: 10.7 - 11.3% Soluble in alcohol, esters, ketones and glycol ethers.
AM grades
 
Nitrogen content: 11.3 - 11.8% Soluble in esters, ketones and glycol ether; highly compatible and dilutable with alcohols.
E-grades
 
Nitrogen content: 11.8 - 12.3% * Soluble in esters, ketones and glycol ethers; dilutable with alcohols.

 

* The maximum permissible nitrogen content is governed by national legislation and varies from country to country between 12.2 % and 12.6 %.

The degree of substitution is coded differently in various regions:


 

Europe
USA/ APAC
GB, India, APAC
A SS M
AM AS L
E RS H